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James Jeans -
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In the interior of the atom, Bohr had tried the plan of retaining the particle-electron and modifying the classical mechanics. Heisenberg took the opposite course, his procedure amounting in effect to retaining the classical mechanics, at least in form, and modifying the electron. Actually, the electron dropped out all together, because it exists only as a matter of inference and not of direct observation. For the same reason, the new theory contains no mention of atoms, nuclei, protons, or of electricity in any shape or form. The existences of all these are matters of inference, and Heisenberg's purely mathematical theory could no more make contact with them than with the efficiency of a turbine or with the price of wheat.
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A similar situation occurred in astronomy, where the Newtonian law of gravitation had been found to predict the orbits of the outer planets with great accuracy, but had failed with the orbits of Mercury and Venus. The relativity theory of gravitation had provided the necessary modification of Newton's law, and in working out the details of the new theory, Einstein had utilized the fact that Newtonian law gave the right result at great distances from the sun. Heisenberg, confronted with a similar problem, was able to avail himself of the fact that the classical mechanics gave the right result at great distances from the atomic nucleus. Here, and here alone Heisenberg's theory made contact with the world of the older physics.
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... experimental physics was particularly interested in the processes taking place inside the atom, and in this field the classical mechanics was failing conspicuously and completely. Perhaps its most spectacular failure was with the fundamental problem with the structure of the atom.
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The main result reached by the new theory was that the classical mechanics can be made to account for the whole range of spectral phenomena, provided entirely new meanings are given to such symbols as p and q which had hitherto been taken to describe the position and motion of the electron.... The most significant of the new properties is that the product pq is no longer the same as the product qp - in other words the order in which the two factors are multiplied together is no longer a matter of indifference. The difference between pq and qp is found to be always the same, being Plank's constant h multiplied by a numerical multiplier.
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The classical mechanics had envisaged the world constructed of matter and radiation, the matter consisting of atoms and the radiation of waves. Plank's theory called for an atomicity of radiation similar to that which was so well established for matter. It supposed that radiation was not discharged from matter in a steady stream like water from a hose, but rather like lead from a machine-gun; it came off in separate chunks which Plank called quanta. This... carried tremendous philosophical consequences.
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Precisely similar ideas are applicable to the molecules that form the air in a room.... The classical mechanics now predicts that the whole energy of motion will be changed into radiation [heat], so that the molecules will shortly be found lying at rest on the floor... In actual fact they continue to move with undiminished energy, forming a perpetual-motion machine in defiance of classical mechanics.... We have passed from one to another of three worlds... from the man-sized world to the world of the electron.
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A second conspicuous landmark... is the enunciation of the fundamental law of radioactive disintegration by Rutherford and Soddy in 1903. This law was in no sense a consequence or development of Plank's theories; indeed fourteen years were to elapse before any connection was noticed between the two. The new law asserted that the atoms of radioactive substances broke up spontaneously, and not because of any particular conditions or special happenings. This seemed to involve an even more startling break with classical theory than the new laws of Plank; radioactive break-up appeared to be an effect without a cause, and suggested that the ultimate laws of nature were not even causal.
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This fallacious result is not... a peculiarity of classical mechanics; it is given also by a very wide class of possible systems of mechanics. This being so, no minor modification of the classical mechanics can possibly put things right. Something far more drastic is needed; we are called upon to surrender either the continuity or the causality of classical mechanics, or else the possibility of representing changes by motions in time and space.
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Bohr had... discovered that the frequencies corresponding to very large integers could be calculated accurately from the classical mechanics; they were simply the number of times that an ordinary electron would complete the circuit of its orbit in one second when it was at a very great distance from the nucleus of the atom to which it belonged. This could only mean that when an electron receded to a great distance from the nucleus of its atom, it not only assumed the properties of an ordinary electron, but also behaved as directed by the classical mechanics. Yet the classical mechanics failed completely for the calculation of frequencies corresponding to small orbits.
James Jeans
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The Constitution was the expression not only of a political faith, but also of political fears. It was wrought both as the organ of the national interest and as the bulwark of certain individual and local rights.
Herbert Croly
James Jeans
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Born:
September 11, 1877
Died:
September 16, 1946
(aged 69)
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